Chemical Physics

Photochemical formation of complexed HNO in low temperature matrices

RP Müller, S Murata, JR Huber

Index: Mueller, R. P.; Murata, S.; Huber, J. Robert Chemical Physics, 1982 , vol. 66, p. 237 - 242

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Citation Number: 13

Abstract

Abstract The molecule HNO complexed to N-methylenemethylamine (H 2 C N CH 3) was prepared by photolyzing N, N-dimethylnitrosamine [(CH 3) 2 N NO] in low temperature matrices. The infrared absorptions of six isotopic such complexed HNO species were measured and assigned. Based on these results a complex between HNO and the amine involving a hydrogen bond is proposed. The bands associated with the hydrogen bond, N ...