Preparation and proposed structure for bis [bis (dimethylamino) bromoborane]-tris (titanium tetrabromide)

MR Suliman, EP Schram

Index: Gmelin Handbook: B: B-Verb.3, 10.4.4.1, page 174 - 175 Show Details Suliman, M. R.; Schram, E. P. Inorganic Chemistry, 1973 , vol. 12, p. 920 - 922

Full Text: HTML

Citation Number: 2

Abstract

Treatment of [(CH,), N], BBr with TiBr, affords {[(CH3), N], BBr),{TiBr4},. The stoichiometry of the latter was established by determination of the reactant ratio and by nucleophilic degradation affording TiBr,. N (CH,), and [(CH,), N], BBr. A structure is proposed for {[(CH,), N], BBr),{TiBr4}, base&on infrared assignments and the unusual stoichiometry of this compound.