The Mechanism of Fluorination. IV. 1 The Effect of Temperature and of Fluorine Concentration upon the Olefin Dimerization Reaction. A New Fluorination Apparatus2
WT Miller, JO Stoffer, G Fuller…
Index: Miller,W.T. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 51 - 56
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Citation Number: 18
Abstract
The interrelated effects of temperature and fluorine concentration on fluorine-olefin reactions have been investigated with some perhaloolefins. Reactions were carried out at low temperatures in a new apparatus which was equipped with a novel high speed nickel gauze stirrer, gas disperser. Reproducible results were obtained with weight recoveries of 95% or better. n'ith. CF3CF= CFCF3, increasing the effective fluorine concentration greatly ...
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