The behaviour of chlorofluoroethanes on β-aluminium (III) fluoride: a [36Cl] radiotracer study

H Bozorgzadeh, E Kemnitz, M Nickkho-Amiry…

Index: Bozorgzadeh, Hamid; Kemnitz, Erhard; Nickkho-Amiry, Mahmood; Skapin, Tomaz; Tate, Graeme D.; Winfield, John M. Journal of Fluorine Chemistry, 2001 , vol. 112, # 2 p. 225 - 232

Full Text: HTML

Citation Number: 11

Abstract

A [36Cl] radiotracer study of the behaviour of 1, 1, 2-trichlorotrifluoroethane on β-aluminium (III) fluoride at elevated temperature indicates that the isomerisation of CCl2FCClF2 to CCl3CF3 occurs by an intramolecular process. Isomerisation is followed by dismutation of CCl3CF3 to give CCl2FCF3 and CCl3CClF2. In neither reaction, surface Al–Cl groups are formed. The compound CCl3CClF2 undergoes further reaction, readily, apparently also ...

Aluminium chloride induced isomerisation of 1, 1, 2-trichlorotrifluoroethane and 1, 2-difluorotetrachloroethane

[Paleta, Oldrich; Liska, Frantisek; Posta, Antonin; Dedek, Vaclav Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 1 p. 104 - 114]

Addition of iodine halides to fluorinated olefins. I. The direction of addition of iodine monochloride to perhaloölefins and some related reactions

[Hauptschein,M. et al. Journal of the American Chemical Society, 1961 , vol. 83, p. 2495 - 2500]

Reaction of 1, 1, 2-trichloro-1, 2, 2-trifluoroethane and other fluorohalocarbons with aluminum halides in the presence and absence of additives. Distinction in …

[Okuhara,K. Journal of Organic Chemistry, 1978 , vol. 43, p. 2745 - 2749]