Russian journal of general chemistry

Unexpected transformations of alkyldiallylamines in the KOH-DMSO system

GK Musorin

Index: Musorin Russian Journal of General Chemistry, 2003 , vol. 73, # 10 p. 1576 - 1577

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Abstract

Abstract Triallylamine in the KOH-DMSO system readily isomerizes into tri (1-propenyl) amine. Alkyldi-allylamines in the same system give 1-ethyl-3-methylcyclohexane along with alkyldi (1-propenyl) amine. Theeffect of quantity of base, reaction temperature on product ratio was studied. A route of 1-ethyl-3-methyl-cyclohexane formation was proposed.