Behavior of Allylamines in the System KOH-DMSO
GK Musorin
Index: Musorin Russian Journal of Organic Chemistry, 2003 , vol. 39, # 7 p. 915 - 918
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Citation Number: 2
Abstract
Abstract Isomerization of triallylamine in the system KOH-DMSO at 90-100° C leads to formation of tris-(1-propenyl) amine in quantitative yield. Under similar conditions, diallyl (ethyl) amine is converted into ethyl-bis (1-propenyl) amine, 1-ethyl-3-methylcyclohexane. Diallylamine in KOH-DMSO gives rise to a complexmixture of products consisting of bis (1- propenyl) amine, methylbis (1-propenyl) amine, 1-ethyl-3-methylcyclo-hexane, and 2-ethyl ...
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