A chiral adamantanophane: preparation, enantiomer separation, theoretical and experimental circular dichroism and absolute configuration
S Grimme, R Lemmerz, F Vögtle
Index: Chemische Berichte, , vol. 127, # 10 p. 2081 - 2088
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Citation Number: 7
Abstract
... Figure 1. Energy-minimized structure (AM1) of 5c, P = pilot atom, A, B, C = descending priority of atoms in the chirality plane ... 109.5' (AM1 These distor- tions are induced by the close proximity of the intraannular adamantane methylene group (C-10) to the ... 1994, 127, 2081-2088 ...
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