Carbenes in polycyclic systems: generation and fate of potential adamantane??1, 3??dicarbenes

…, J Veljković, K Mlinarić??Majerski

Index: Klaic, Lada; Aleskovic, Marija; Veljkovic, Jelena; Mlinaric-Majerski, Kata Journal of Physical Organic Chemistry, 2008 , vol. 21, # 4 p. 299 - 305

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Citation Number: 8

Abstract

Abstract Potential formation and reactions of adamantane-1, 3-dicarbenes 1–3 generated under different conditions and from different precursors, such as sodium salt of adamantane- 1, 3-dicarbaldehyde ditosylhydrazone (4a), sodium salt of 1, 3-diacetyladamantane ditosylhydrazone (5a), sodium salt of 1, 3-dibenzoyladamantane ditosylhydrazone (6a), and 1, 3-bis (diazobenzyl) adamantane (7) are reported. Carbene species generated thermally ...