PEG??4000??promoted palladium??catalyzed N??allylation in water: aminonaphthalene as an example

…, YJ Shue, SY Yang, SC Yang

Index: Shih, Chun-Jen; Shue, Yi-Jen; Yang, Shiang-Yu; Yang, Shyh-Chyun Applied Organometallic Chemistry, 2012 , vol. 26, # 10 p. 550 - 555

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Abstract

Allylamines are pivotal building blocks for various biological properties and advanced intermediates in total synthesis of natural products [1] and especially those involving ring- closing metathesis.[2] Therefore their synthesis is still an important area of activity. Palladium- catalyzed transformations of allylic compounds have demonstrated powerful and well- established synthetic procedures for carbon–carbon and carbon–heteroatom (N, O, S) ...