Direct palladium (0)-catalyzed amination of allylic alcohols with aminonaphthalenes
YJ Shue, SC Yang, HC Lai
Index: Shue, Yi-Jen; Yang, Shyh-Chyun; Lai, Hwe-Chen Tetrahedron Letters, 2003 , vol. 44, # 7 p. 1481 - 1485
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Citation Number: 38
Abstract
The direct activation of C O bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium reagents. The palladium-catalyzed amination of allylic alcohols using aminonaphthalenes gave N-allylic naphthylamines in good yields. The monoallylation products are formed in the main.
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