The Addition of Silicon Hydrides to Olefinic Double Bonds. IX. Addition of sym-Tetramethyldisiloxane to Hexene-1,-2, and-3
HM Bank, JC Saam, JL Speier
Index: Bank,H.M. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 792 - 794
Full Text: HTML
Citation Number: 27
Abstract
sym-Tetramethyldisiloxane adds to either hexene-2 or hexene-3 in the presence of chloroplatinic acid to establish Si-C bonds with the silicon attached chiefly to the 1-position but also to the 2-and 3-positions of the hexyl group in the products. Hexene-1 formed the 1- hexyl derivative almost exclusively. During the reaction a hexene becomes a mixture of hexene isomers.
Related Articles:
Synthesis of (E)-alkenes via hydroindation of CC in InCl 3–NaBH 4 system
[Wang, Chunyan; Yan, Lei; Zheng, Zhiguo; Yang, Deyu; Pan, Yuanjiang Tetrahedron, 2006 , vol. 62, # 33 p. 7712 - 7717]
[Matsuda, Isamu; Kato, Tomohisa; Sato, Susumu; Izumi, Yusuke Tetrahedron Letters, 1986 , vol. 27, # 47 p. 5747 - 5750]
[Musolf,M.C.; Speier,J.L. Journal of Organic Chemistry, 1964 , vol. 29, p. 2519 - 2524]
[Musolf,M.C.; Speier,J.L. Journal of Organic Chemistry, 1964 , vol. 29, p. 2519 - 2524]