Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions

K Parkhomenko, L Barloy, JB Sortais, JP Djukic…

Index: Parkhomenko, Ksenia; Barloy, Laurent; Sortais, Jean-Baptiste; Djukic, Jean-Pierre; Pfeffer, Michel Tetrahedron Letters, 2010 , vol. 51, # 5 p. 822 - 825

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Citation Number: 8

Abstract

Various cycloruthenated complexes were used as homogeneous catalysts for the atom- transfer radical addition of polyhalogenated compounds to several olefinic substrates. Yields obtained through conventional or microwave heating could reach high values (up to 98% with CBrCl3 and 88% with CCl4).

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