The Journal of Organic Chemistry

Free-radical reactions of fluoroalkanesulfenyl halides. 4. Reactions of perfluoroalkane-and pentafluorobenzenesulfenyl chlorides with hydrocarbons in the presence of …

JF Harris Jr

Index: Harris, J. F. Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 268 - 271

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Citation Number: 9

Abstract

Free-radical reactions of perfluoroalkanesulfenyl chlorides and pentafluorobenzenesulfenyl chloride with cyclohexane and toluene were carried out in the presence of bis (perfluoroalky1) disuliidea and bis (pentatluoropheny1) disulfide to asaem the competition between the disulfide and the sulfenyl chloride for reaction with hydrocarbon radicals. With added bis (perfluoroalky1) disulfides, radical attack occurs only on the eulfenyl chloride, ...

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