The Free-radical Addition of Trifluoromethanesulfenyl Chloride to Haloölefins
JF Harris
Index: Harris,J.F. Journal of the American Chemical Society, 1962 , vol. 84, p. 3148 - 3153
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Citation Number: 52
Abstract
The addition of sulfenyl halides to hydrocarbon olefins to give p-haloalkyl sulfides is well known. 2 The evidence thus far obtained indicates that the reaction is an ionic one and that the mechanism involves attack by the electrophilic sulfenium group upon the electron-rich double bond, generally resulting in the predominant (and sometimes exclusive) formation of a single isomer (the XIarkownikoff isomer). Apparently very little attention has been given ...
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