Synthesis of arylstannanes from arylamines

AB Chopa, MT Lockhart, G Silbestri

Index: Chopa, Alicia B.; Lockhart, Maria T.; Silbestri, Gustavo Organometallics, 2001 , vol. 20, # 15 p. 3358 - 3360

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Citation Number: 35

Abstract

Triorganostannyl anions have proved to be excellent nucleophiles in S RN 1 reactions. 2 We have recently described the photostimulated reactions of haloarenes and haloheteroarenes with triphenylstannyl anions in dimethyl sulfoxide 3 and the photostimulated reactions of aryldiethyl phosphate esters with trimethyl- and triphenylstannyl anions in liquid ammonia. 4 All these substrates, under the reaction conditions studied, gave substitution products in good to ...