Sulphur substituted organotin compounds. Part 9. Crystal and molecular structure and reactions of [(p-chlorophenylthio) methyl] tricyclohexylstannane

…, SMSV Doidge-Harrison, IW Nowell, RA Howie…

Index: Cox, Philip J.; Doidge-Harrison, Solange M. S. V.; Nowell, Ian W.; Howie, R. Alan; Randall, Andrew P.; Wardell, James L. Inorganica Chimica Acta, 1990 , vol. 172, p. 225 - 232

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Citation Number: 14

Abstract

Abstract The crystal and molecular structure of [(p-chlorophenylthio) methyl] tricyclohexylstannane (II) has been determined. In the two independent molecules of monoclinic II there are slightly distorted tetrahedral geometries about tin with intramolecular Sn S distances of 3.29 (1) and 3.26 (1) Å. Compound II reacts with N-bromosuccinimide, I 2, Pb (OAc) 4 or CF 3 CO 2 H to give XCH 2 SC 6 H 4 Cl-p (X= Br, I, AcO or H) and the ...