General ketone synthesis. Reaction of organocopper reagents with S-alkyl and S-aryl thioesters
RJ Anderson, CA Henrick…
Index: Anderson,R.J. et al. Journal of the American Chemical Society, 1974 , vol. 96, p. 3654 - 3655
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Citation Number: 83
Abstract
The thioester was added rapidly to the preformed copper (1) reagent. Reactions were quenched at the stated temperature by dropwise addition of aq NH, Cl.* Yield after distillation unless otherwise noted. c Satisfactory infrared, nmr, and mass spectral analyses were obtained. All thioesters in this report were prepared in essentially quantitative yield from the corresponding acid chloride and 1 equiv of thiol in ether in the presence of 1 to 2 ...
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