Selective Alkene Oxidation with H2O2 and a Heterogenized Mn Catalyst: Epoxidation and a New Entry to Vicinal cis??Diols
DE De Vos, S de Wildeman, BF Sels…
Index: De Vos, Dirk E.; De Wildeman, Stefaan; Sels, Bert F.; Grobet, Piet J.; Jacobs, Pierre A. Angewandte Chemie - International Edition, 1999 , vol. 38, # 7 p. 980 - 983
Full Text: HTML
Citation Number: 126
Abstract
Abstract Covalent anchoring of 1, 4-dimethyl-1, 4, 7-triazacyclononane on silica gel is the first step in the preparation of a heterogenized Mn catalyst. When H 2 O 2 is used as the oxidant, this material can catalyze the vicinal cis-dihydroxylation of disubstituted olefins, as shown schematically here. Both enantiomers of the product are obtained.
Related Articles:
Investigations of the reaction mechanisms of 1, 2-indanediones with amino acids
[Petrovskaia; Taylor; Hauze; Carroll; Joullie Journal of Organic Chemistry, 2001 , vol. 66, # 23 p. 7666 - 7675]
A Novel Synthesis of Indandiones Using the HOF⊙ CH3CN Complex
[Dayan, Sharon; Almog, Joseph; Khodzhaev, Oleg; Rozen, Shlomo Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2752 - 2754]
Emulation of racemase activity by employing a pair of stereocomplementary biocatalysts
[Gruber, Christian C.; Nestl, Bettina M.; Gross, Johannes; Hildebrandt, Petra; Bornscheuer, Uwe T.; Faber, Kurt; Kroutil, Wolfgang Chemistry - A European Journal, 2007 , vol. 13, # 29 p. 8271 - 8276]
[Almog, Joseph; Zehavy, Yirmi; Cohen, Shmuel Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3285 - 3288]
[Almog, Joseph; Zehavy, Yirmi; Cohen, Shmuel Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3285 - 3288]