Investigations of the reaction mechanisms of 1, 2-indanediones with amino acids
O Petrovskaia, BM Taylor, DB Hauze…
Index: Petrovskaia; Taylor; Hauze; Carroll; Joullie Journal of Organic Chemistry, 2001 , vol. 66, # 23 p. 7666 - 7675
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Citation Number: 44
Abstract
The reaction mechanisms of amino acids with a new class of fluorogenic reagents were investigated. The structures of colored and fluorescent species formed in these reactions were partially confirmed by experimental evidence. Reaction intermediates, CNC 1, 3- dipoles derived from imines, were trapped with dipolarophiles in 3+ 2 cycloadditions to form spiropyrrolidines.
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