Facile conversion of tosylhydrazones to the carbonyl compounds using peroxysulfur intermediate

YH Kim, HK Lee, HS Chang

Index: Kim, Yong Hae; Lee, Hyeon Kyu; Chang, Hae Sung Tetrahedron Letters, 1987 , vol. 28, # 37 p. 4285 - 4288

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Citation Number: 16

Abstract

Abstract Various tosylhydrazones, such as dialkyl and aryl-alkyl tosylhydrazones, were found to react with a peroxysulfur intermediate, which was generated by the reaction of 2- nitrobenzenesulfonyl chloride with superoxide, to be converted into the corresponding carbonyl compounds, in mostly quantitative yields, at− 30 C under mild conditions.