Ligand coupling reactions of 2-pyridyl, 4-pyridyl and 2-pyrimidyl sulfoxides with Grignard reagents

…, T Takeda, J Uenishi, S Wakabayashi

Index: Oae, Shigeru; Takeda, Takeshi; Uenishi, Junichi; Wakabayashi, Shoji Phosphorus, Sulfur and Silicon and Related Elements, 1996 , vol. 115, p. 179 - 182

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Abstract

Abstract The ligand coupling reaction was extended to 3-and 4-pyridyl sulfoxides as well as the 2-pyrimidyl moiety with Grignard reagents. It was found that both 4-pyridyl and 2- pyrimidyl sulfoxides nicely underwent the ligand coupling reactions, but 3-pyridyl sulfoxide underwent ligand exchange.

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