Crystal Growth & Design

On the mesophase formation of 1, 3-dialkylimidazolium ionic liquids

M Yang, B Mallick, AV Mudring

Index: Yang, Mei; Mallick, Bert; Mudring, Anja-Verena Crystal Growth and Design, 2013 , vol. 13, # 7 p. 3068 - 3077

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Citation Number: 18

Abstract

A series of seven different 1, 3-dialkylimidazolium-based ion-pair salts with the same molecular weight and size but different symmetries was synthesized. For all salts, bromide was chosen as the counterion, giving the series ([C n IMC m][Br]), where IM= imidazolium and C n and C m are varying N-alkyl substituents with n+ m= 13. The effect of symmetry on the physicochemical properties is investigated herein.

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