A convenient, general synthesis of. alpha.-trichloromethyl carbinols
…, GG Hazen, LM Weinstock
Index: Wyvratt, Jean M.; Hazen, George G.; Weinstock, Leonard M. Journal of Organic Chemistry, 1987 , vol. 52, # 5 p. 944 - 945
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Citation Number: 33
Abstract
carbonyl compound yieldFb% 3-nitrobenzaldehyde 90 benzaldehyde 99 4-anisaldehyde 97 isobutyraldehyde 70 cyclohexanone 68 a All products exhibited the expected lH and 13C NMR and MS characteristics. Isolated yields after distillation or crystallization. alcohol in 72% The generation of trichloromethide anion in solution from the decomposition of trichloroacetic acid in dimethyl sulfoxide has been used to prepare a-(trichloromethyl)-4- ...
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