Arylation of olefins by N-nitroso-N-arylacetamides under palladium (0) catalysis: a new precursor of arylpalladium species

K Kikukawa, M Naritomi, GX He, F Wada…

Index: Kikukawa, Kiyoshi; Naritomi, Masaki; He, Gong-Xin; Wada, Fumio; Matsuda, Tsutomu Journal of Organic Chemistry, 1985 , vol. 50, # 3 p. 299 - 301

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Citation Number: 34

Abstract

Olefins (styrene, octene-1, cycloheptene, ethyl acrylate, and vinyl acetate) were easily arylated in good yields with N-nitroso-N-arylacetamides (ArN (N0) COCHG Ar= Ph, 4- MeCsH4, 4-MeOCsH4, 4-C1C6H4, 4-BrCsH4, and 4-1C6H4) under palladium (0) catalysis at 40" C within 40 min.

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