Comparison of Homogeneous and Heterogeneous Catalysts for Glucose??to??Fructose Isomerization in Aqueous Media
V Choudhary, AB Pinar, RF Lobo, DG Vlachos…
Index: Choudhary, Vinit; Pinar, Ana B.; Lobo, Raul F.; Vlachos, Dionisios G.; Sandler, Stanley I. ChemSusChem, 2013 , vol. 6, # 12 p. 2369 - 2376
Full Text: HTML
Citation Number: 44
Abstract
Abstract Herein, the first comparison of the mechanisms of glucose-to-fructose isomerization in aqueous media enabled by homogeneous (CrCl 3 and AlCl 3) and heterogeneous catalysts (Sn-beta) by using isotopic-labeling studies is reported. A pronounced kinetic isotope effect (KIE) was observed if the deuterium label was at the C2 position, thus suggesting that a hydrogen shift from the C2 to C1 positions was the rate-limiting step with ...
Related Articles:
Relative and absolute kinetic studies of 2-butanol and related alcohols with tropospheric Cl atoms
[Ballesteros, Bernabe; Garzon, Andres; Jimenez, Elena; Notario, Alberto; Albaladejo, Jose Physical Chemistry Chemical Physics, 2007 , vol. 9, # 10 p. 1210 - 1218]
Relative and absolute kinetic studies of 2-butanol and related alcohols with tropospheric Cl atoms
[Ballesteros, Bernabe; Garzon, Andres; Jimenez, Elena; Notario, Alberto; Albaladejo, Jose Physical Chemistry Chemical Physics, 2007 , vol. 9, # 10 p. 1210 - 1218]
Relative and absolute kinetic studies of 2-butanol and related alcohols with tropospheric Cl atoms
[Ballesteros, Bernabe; Garzon, Andres; Jimenez, Elena; Notario, Alberto; Albaladejo, Jose Physical Chemistry Chemical Physics, 2007 , vol. 9, # 10 p. 1210 - 1218]
[Taqui Khan; Halligudi; Nageswara Rao; Shukla Journal of molecular catalysis, 1989 , vol. 51, # 2 p. 161 - 170]
Radiolytic decomposition of solid oxalic acid
[Gal, O.; Baugh, P. J.; Phillip, G. O. International Journal of Applied Radiation and Isotopes, 1971 , vol. 22, p. 321 - 324 Full Text View citing articles Show Details Gal, O.; Petkovic, L.; Josimovic, L.; Draganic, I. International Journal of Applied Radiation and Isotopes, 1968 , vol. 19, p. 645 - 656 Full Text View citing articles Show Details Sugimori, A. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, p. 2583 - 2588 Full Text Show Details Gmelin Handbook: C: MVol.C4, 7.5.5.3, page 213 - 214]