Buchwald–Hartwig Amination of (Hetero) aryl Chlorides by Employing Mor??DalPhos under Aqueous and Solvent??Free Conditions
BJ Tardiff, M Stradiotto
Index: Tardiff, Bennett J.; Stradiotto, Mark European Journal of Organic Chemistry, 2012 , # 21 p. 3972 - 3977
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Citation Number: 15
Abstract
Abstract We report on the application of the [Pd (cinnamyl) Cl] 2/Mor-DalPhos catalyst system in the Buchwald–Hartwig amination of (hetero) aryl chlorides with primary or secondary amines conducted either under aqueous conditions without the use of co- solvents and/or surfactants or under solvent-free conditions (52 examples). We have established that reactions of this type can be conducted without the rigorous exclusion of ...
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