Synthesis

Trans-spanned palladium catalyst for mild and efficient amination of aryl halides with benzophenone imine

O Grossman, K Rueck-Braun, D Gelman

Index: Grossman, Olga; Rueck-Braun, Karola; Gelman, Dmitri Synthesis, 2008 , # 4 p. 537 - 542

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Citation Number: 8

Abstract

Abstract A new protocol for palladium-catalyzed Buchwald-Hartwig amination of aryl chlorides and bromides with benzophenone imine as ammonia surrogate is described. The suggested reaction conditions are mild and may therefore be applied to a variety of sensitive starting materials.

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