1, 4-Bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadienes as strong salt-free reductants for generating low-valent early transition metals with electron-donating ligands
T Saito, H Nishiyama, H Tanahashi…
Index: Estevez, Rosa E.; Paradas, Miguel; Millan, Alba; Jimenez, Tania; Robles, Rafael; Cuerva, Juan M.; Oltra, J. Enrique Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1616 - 1619
Full Text: HTML
Citation Number: 30
Abstract
... J. Am. Chem. Soc. ... figure Figure 3. Cyclic voltammogram of organosilicon compounds 1b, 2a–c, 3, and 4 in CH 2 Cl 2 ([organosilicon] = 5 mM, [ n Bu 4 N][PF 6 ] = 0.1 M, scan rate = 100 mV/s). Redox potential (E 1/2 ) of the organosilicon compounds: + 0.83 V (1b, anodic ...
Related Articles:
Decarboxylative aldol reactions of allyl β-keto esters via heterobimetallic catalysis
[Lou, Sha; Westbrook, John A.; Schaus, Scott E. Journal of the American Chemical Society, 2004 , vol. 126, # 37 p. 11440 - 11441]
Chemistry of aldolate dianions. Effects of. beta.-heteroatom substituents on ketone enolization
[Van Martin; Murray, Desmond H.; Pratt, Norman E.; Zhao, Yun-Bo; Albizati, Kim F. Journal of the American Chemical Society, 1990 , vol. 112, # 19 p. 6965 - 6978]
Mevalonolactone derivatives as inhibitors of 3-hydroxy-3-methylglutaryl coenzyme A reductase.
[Sato; Ogiso; Noguchi; Mitsui; Kaneko; Shimada Chemical and pharmaceutical bulletin, 1980 , vol. 28, # 5 p. 1509 - 1525]
[Boldrini, Gian Paolo; Lodi, Luisa; Tagliavini, Emilio; Trombini, Claudio; Umani-Ronchi, Achille Journal of Organometallic Chemistry, 1987 , vol. 336, p. 23 - 28]