The modes of. beta.-silyl involvement in solvolysis

JB Lambert, RB Finzel

Index: Lambert, Joseph B.; Finzel, Rodney B. Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 2020 - 2022

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Citation Number: 50

Abstract

Communications to the Editor J. Am. Chem. SOC.. Vol. 104, No. 7, 1982 2021 is a conformational mixture of two forms. The cis molecule has a gauche relationship between silicon and the leaving group in both forms (3 and 3'), so that neither vertical nor nucleophilic participation is possible. 15 The trans molecule exists as an equilibrium between the gauche diequatorial form and the anti diaxial form 4. The latter is not destabilized by the ...