Journal of Organometallic Chemistry

Effects of varying the media for base cleavage of some Benzyl-silicon and-tin compounds in alcohols

C Eaborn, FMS Mahmoud

Index: Eaborn, Colin; Mahmoud, Foad M.S. Journal of Organometallic Chemistry, 1981 , vol. 206, # 1 p. 49 - 58

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Citation Number: 30

Abstract

Abstract The effects on the rates of cleavage of 3-ClC 6 H 4 CH 2 MMe 3 and 3, 5-Cl 2 C 6 H 3 CH 2 MMe 3 compounds with M= Si and Sn have been examined for (a) various concentrations of NaOMe-MeOH;(b) various concentrations of H 2 O in NaOHH 2 O-eOH; and (c) variation of R from Me to Et, i-Pr and t-Bu for metal alkoxide-ROH mixtures. Rates have also been measured for cleavages in NaOCH 2 CF 3 HOCH 2 CF 3-Me 2 SO. In all ...