Nickel-catalysed electrochemical coupling between mono-or di-chlorophenylphosphines and aryl or heteroaryl halides

Y Budnikova, Y Kargin, JY Nédélec…

Index: Budnikova, Yulia; Kargin, Yuri; Nedelec, Jean-Yves; Perichon, Jacques Journal of Organometallic Chemistry, 1999 , vol. 575, # 1 p. 63 - 66

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Citation Number: 36

Abstract

Aryl and heteroaryl tertiary phosphines are useful ligands in homogeneous catalysis. The presence of phenyl groups substituted with various functionalities is of great interest to modify the electronic properties of the ligand and then modulate the reactivity of the metallic centre associated with it, or to give access to precursors of hydrosoluble complexes, or to prepare ligands which can be immobilised easily. Also mixed aryl-heteroaryl phosphines combining the complexing ...

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