Observations on the reactivity of thiyl radicals derived from 3, 6-epidithiodiketopiperazine-2, 5-diones and related congeners

…, WB Motherwell, P Potier, C Pradet, DL Selwood

Index: Hilton; Motherwell; Potier; Pradet; Selwood Bioorganic and Medicinal Chemistry Letters, 2005 , vol. 15, # 9 p. 2239 - 2242

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Citation Number: 9

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A range of thiyl radicals derived from the reduced form of epidithiodiketopiperazines (ETPs) act as polarity reversal catalysts for the hydrosilylation of an enol lactone but not for H-atom abstraction from a model ribose ester. ... A range of thiyl radicals derived from the reduced form of ...