Benzoyl trifluoromethanesulphonate. A highly efficient benzoylating agent for sterically hindered hydroxy groups

M Koreeda, L Brown

Index: Koreeda, Masado; Brown, Lindsey Journal of the Chemical Society, Chemical Communications, 1983 , # 19 p. 1113 - 1115

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Abstract

Reactions of benzoyl trifluoromethanesulphonate (BzOTf) with a variety of alcohols, including some with sterically hindered secondary and tertiary hydroxy goups, with phenolic compounds, and with 1, 2-diols at low temperatures provide the corresponding benzoates in high yield.

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