Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4- …
T Shintou, W Kikuchi, T Mukaiyama
Index: Shintou, Taichi; Kikuchi, Wataru; Mukaiyama, Teruaki Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 8 p. 1645 - 1667
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Citation Number: 56
Abstract
A new-type of oxidation–reduction condensation proceeded smoothly to afford carboxylic acid alkyl esters or alkyl phenyl ethers in good to high yields by combined use of alkoxydiphenylphosphines (1) having primary, bulky secondary or tertiary alkoxy groups, a mild quinone-type oxidant such as 2, 6-dimethyl-1, 4-benzoquinone (DMBQ) and carboxylic acids or phenols. Generally, alkoxydiphenylphosphines were prepared easily from ...
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