Amide-directed hydrocarbonylation of N-alkenylamides and α-alkenyllactams

I Ojima, Z Zhang

Index: Ojima, Iwao; Zhang, Zhaoda Journal of Organometallic Chemistry, 1991 , vol. 417, # 1/2 p. 253 - 276

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Citation Number: 30

Abstract

Abstract The amide-directed Rh-catalyzed hydroformylation and Pd-catalyzed hydroesterification of N-allylamides give the iso-aldehyde and ester, respectively, with good regioselectivity. The Rh-and Co 2 Rh 2 (CO) 12-catalyzed reactions of N-methallylamide ...