Diels-Alder reactions of 1-azadienes

YS Cheng, AT Lupo Jr, FW Fowler

Index: Cheng,Y.S.; Lupo,A.T.; Fowler,F.W. Journal of the American Chemical Society, 1983 , vol. 105, p. 7696

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Citation Number: 77

Abstract

Abstract: N-Acyl-1-azadienes have been prepared by the thermal elimination of acetic acid from 0-acetylhydroxylamine derivatives. These reactive compounds have been observed to undergo the intramolecular Diels-Alder reaction to give piperidine derivatives. Studies on substituted azadienes suggest that the reaction follows predominantly an exo stereochemical pathway.