Bulletin of the Chemical Society of Japan

Reaction of thioaldehydes with amines

K Okuma, Y Komiya, H Ohta

Index: Okuma, Kentaro; Komiya, Yasuo; Ohta, Hiroshi Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2402 - 2406

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Citation Number: 10

Abstract

The reaction of phosphonium ylides with elemental sulfur gave thioaldehydes, which changed to the corresponding thioamides in good yields when treated with amines. When thioaldehydes containing α-hydrogens were treated with secondary amines, the corresponding enamines or reduction products were obtained.

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