Sur les organometalliques issus de thioamides: I. Reactivite avec les aldehydes et cetones; stereochimie de la condensation avec la t-butyl-4 cyclohexanone et le …

…, N Goasdoue, M Gaudemar, M Mladenova

Index: Goasdoue, Claude; Goasdoue, Nicole; Gaudemar, Marcel; Mladenova, Margarita Journal of Organometallic Chemistry, 1981 , vol. 208, # 3 p. 279 - 292

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Citation Number: 29

Abstract

Abstract Organometallic compounds derived from thioamides RCH 2 CSN (R 3) 2 condense normally with aldehydes and saturated ketones. Condensation with 4-t-butyl-cyclohexanone leads predominantly to equatorial attack by the organometallic compound. These results suggest that the organometallic structure as RCH C (SM) N (R 3) 2.