1, 4-Addition reaction of organolithium and-magnesium compounds to. alpha.,. beta.-unsaturated thioamides

Y Tamaru, T Harada, H Iwamoto…

Index: Tamaru,Y. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 5221 - 5223

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Citation Number: 55

Abstract

Thioamides have already been shown to be easily convertible to a variety of types of compounds (eg, amines,'enamines, 2 ketene SN-acetal~,~ amide^,^ etc.) and fully proved to be synthetically potential by the total syntheses of vitamin B125 and indole alkaloids. 6 During the course of our study to explore further versatility of thioamides, lb we have found that a,@-unsaturated thioamides react with organolithium and-magnesium compounds ...

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