Study of the complexing properties toward Ru II of new polydentate amphiphilic phosphines containing polyether chains. Unprecedented η 3 mode of bonding of the …
…, J Suades, B Donadieu, R Mathieu
Index: Valls, Esteve; Suades, Joan; Donadieu, Bruno; Mathieu, Rene Chemical Communications, 1996 , # 6 p. 771 - 772
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Abstract
New polydentate amphiphilic phosphines containing polyether chains are prepared; unprecedented coordinationa and reactivity of the hemilabile ligand PPh [(CH2) 3CHMe2][(CH2CH2O) 3Me] are found; the η3mode of bonding of this ligand is demonstrated by X-ray crystallographic studies.
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