Facile preparation of aryl sulfides using palladium catalysis under mild conditions
T Okauchi, K Kuramoto, M Kitamura
Index: Okauchi, Tatsuo; Kuramoto, Kouji; Kitamura, Mitsuru Synlett, 2010 , # 19 p. 2891 - 2894
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Citation Number: 13
Abstract
Abstract A convenient method for CS cross-coupling of aryl bromides with various thiols has been developed that involves the use of a 1, 1′-bis (diphenylphosphino) ferrocene (DPPF)- ligated palladium complex with N, N-diisopropylethylamine (DIPEA) as the base. This coupling is tolerant of a wide range of functional groups, including hydroxy, amino, cyano, nitro, formyl, and carboxyl groups.
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