Highly Efficient and Functional??Group??Tolerant Catalysts for the Palladium??Catalyzed Coupling of Aryl Chlorides with Thiols
MA Fernández??Rodríguez, Q Shen…
Index: Fernandez-Rodriguez, Manuel A.; Shen, Qilong; Hartwig, John F. Chemistry - A European Journal, 2006 , vol. 12, # 30 p. 7782 - 7796
Full Text: HTML
Citation Number: 184
Abstract
Abstract The cross-coupling reaction of aryl chlorides with aliphatic and aromatic thiols catalyzed by palladium complexes of the strongly binding bisphosphine CyPF-tBu ligand (1) is reported. Most of the reactions catalyzed by complexes of ligand 1 occur with turnover numbers that exceed those of previous catalysts by two orders of magnitude. The reactions occur with excellent yields, broad scope and high tolerance of functional groups. Coupling ...
Related Articles:
Facile preparation of aryl sulfides using palladium catalysis under mild conditions
[Okauchi, Tatsuo; Kuramoto, Kouji; Kitamura, Mitsuru Synlett, 2010 , # 19 p. 2891 - 2894]
Facile preparation of aryl sulfides using palladium catalysis under mild conditions
[Okauchi, Tatsuo; Kuramoto, Kouji; Kitamura, Mitsuru Synlett, 2010 , # 19 p. 2891 - 2894]
[Yoon, Nung Min; Choi, Jaesung; Ahn, Jin Hee Journal of Organic Chemistry, 1994 , vol. 59, # 12 p. 3490 - 3493]
Ionic denithrohydrogenation of α-nitro or β-nitro sulfides with triethylsilane
[Ono, Noboru; Hashimoto, Toshihiro; Jun, Tuo Xiao; Kaji, Aritsune Tetrahedron Letters, 1987 , vol. 28, # 20 p. 2277 - 2280]
Visualizing nanocatalysts in action from color change reaction to magnetic recycling and reuse
[Swapna, Kokkirala; Murthy, Sabbavarapu Narayana; Jyothi, Mocharla Tarani; Nageswar, Yadavalli Venkata Durga Organic and Biomolecular Chemistry, 2011 , vol. 9, # 17 p. 5989 - 5996]