Organolanthanide-catalyzed intra-and intermolecular tandem CN and CC bond-forming processes of aminodialkenes, aminodialkynes, aminoalkeneynes, and …
Y Li, TJ Marks
Index: Li, Yanwu; Marks, Tobin J. Journal of the American Chemical Society, 1998 , vol. 120, # 8 p. 1757 - 1771
Full Text: HTML
Citation Number: 241
Abstract
This contribution describes catalytic tandem CN and CC bond-forming reactions involving the intramolecular hydroamination/bicyclization and intermolecular hydroamination/ cyclization of olefins and alkynes using the organolanthanide complexes Cp'2LnCH (SiMe3) 2 and Me2SiCp''2LnCH (SiMe3) 2 (Cp'= η5-Me5C5; Cp''= η5-Me4C5; Ln= lanthanide) as precatalysts. In the case of the intramolecular processes, substrates of the structures RC⋮ ...
Related Articles:
Synthesis of fused imidazo azepine derivatives by sequential van Leusen/enyne metathesis reactions
[Gracias, Vijaya; Gasiecki, Alan F.; Djuric, Stevan W. Tetrahedron Letters, 2005 , vol. 46, # 52 p. 9049 - 9052]
[Brummond, Kay M.; Chen, Hongfeng; Mitasev, Branko; Casarez, Anthony D. Organic Letters, 2004 , vol. 6, # 13 p. 2161 - 2163]
Synthesis of New Vinyl Thiocyanates by [3, 3] Sigmatropic Rearrangement of Isothiocyanates
[Banert, Klaus; Hagedorn, Manfred; Mueller, Anett European Journal of Organic Chemistry, 2001 , # 6 p. 1089 - 1103]