A Highly Efficient and Selective Aerobic Cross??Dehydrogenative??Coupling Reaction Photocatalyzed by a Platinum (II) Terpyridyl Complex
JJ Zhong, QY Meng, GX Wang, Q Liu…
Index: Zhong, Jian-Ji; Meng, Qing-Yuan; Wang, Ge-Xia; Liu, Qiang; Chen, Bin; Feng, Ke; Tung, Chen-Ho; Wu, Li-Zhu Chemistry - A European Journal, 2013 , vol. 19, # 20 p. 6443 - 6450
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Citation Number: 66
Abstract
Abstract Thanks to the superior redox potential of platinum (II) complex compared with that of Ru (bpy) 3 2+ in the excited state, an efficient and selective visible-light-induced CDC reaction has been developed by using a catalytic amount (0.25%) of 1. With the aid of FeSO 4 (2 equiv), the corresponding amide could not be detected under visible-light irradiation (λ= 450 nm), but the desired cross-coupling product was exclusively obtained under ambient ...
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