Oxidation of dithiocarbamates and synthesis of a stable sulfine
D Chevrie, P Metzner
Index: Chevrie, David; Metzner, Patrick Tetrahedron Letters, 1998 , vol. 39, # 49 p. 8983 - 8986
Full Text: HTML
Citation Number: 17
Abstract
Investigation of the oxidation reaction of various dithiocarbamates demonstrated that the corresponding sulfines (S-oxides) are formed. Though their stabilities are very moderate, a number of sulfines could be isolated andv characterised. When left at ambient temperature they decomposed to thiolocarbamates and dithiocarbamates. The sulfines from secondary dithiocarbamates led to disulfides which formation was explained. With a sterically ...
Related Articles:
Iodide-Catalyzed Synthesis of Secondary Thiocarbamates from Isocyanides and Thiosulfonates
[Nishiyama, Yutaka; Kawamatsu, Hiroaki; Sonoda, Noboru Journal of Organic Chemistry, 2005 , vol. 70, # 7 p. 2551 - 2554]
[Mizuno, Takumi; Iwai, Toshiyuki; Ishino, Yoshio Tetrahedron, 2005 , vol. 61, # 38 p. 9157 - 9163]
[Mizuno, Takumi; Nishiguchi, Ikuzo; Sonoda, Noboru Tetrahedron, 1994 , vol. 50, # 19 p. 5669 - 5680]
A General, Selective Synthesis of Thiol Esters
[D'Amico, John J.; Schafer, Tann Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 301 - 304]
A General, Selective Synthesis of Thiol Esters
[D'Amico, John J.; Schafer, Tann Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 301 - 304]