Solvent-assisted thiocarboxylation of amines and alcohols with carbon monoxide and sulfur under mild conditions
T Mizuno, T Iwai, Y Ishino
Index: Mizuno, Takumi; Iwai, Toshiyuki; Ishino, Yoshio Tetrahedron, 2005 , vol. 61, # 38 p. 9157 - 9163
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Citation Number: 38
Abstract
DMSO or DMF as a solvent strongly accelerated the thiocarboxylation of amines and alcohols with carbon monoxide and sulfur. Under mild conditions (1atm, 20° C), this thiocarboxylation of amines assisted by DMSO with carbon monoxide and sulfur has been developed into a practical and convenient synthetic method for S-alkyl thiocarbamates in good to excellent yields, including EPTC, thiobencarb, orbencarb, and molinate ( ...
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