Journal of the American Chemical Society

Electronic and steric effects in the olefin arylation and carboalkoxylation reactions with organopalladium compounds

RF Heck

Index: Heck,R.F. Journal of the American Chemical Society, 1971 , vol. 93, p. 6896 - 6901

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Citation Number: 95

Abstract

Abstract: The arylation and carboalkoxylation of olefins with aryl-and carboalkoxypalladium compounds to form styrene derivatives and unsaturated esters, respectively, has been further studied in order to better determine the factors affecting the direction of addition of the organic group to the olefin. Generally, the addition appears to be sterically controlled with the effectively larger organic group adding onto the least substituted carbon of the double ...

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