Free Radical Rearrangements in the Decarbonylation of Aldehydes1
DY CURTIN, JC KAUER
Index: Curtin,D.Y.; Kauer,J.C. Journal of Organic Chemistry, 1960 , vol. 25, p. 880 - 885
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Citation Number: 24
Abstract
The reaction of p-deutero-P-(p-anisyl)-j3-phenylpropionaldehyde with di-t-butyl peroxide has been found to give decarbonylation without rearrangement of the deuterium atom.* 4 reinvestigation of the decarbonylation of p, &j3-triphenylpropionaldehyde has shown that in addition to the 1, 1, 2-triphenylethane previously reported there are present lesser amounts of triphenylethylene and 3, 3-diphenyl-l-indanone. Decarbonylation of j3-(pnitrophenyl)-P, ...
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