Silicon in benzamide directed ortho metalation. Formation and reactions of benzamide benzynes
K Shankaran, V Snieckus
Index: Shankaran, K.; Snieckus, V. Tetrahedron Letters, 1984 , vol. 25, # 27 p. 2827 - 2830
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Citation Number: 24
Abstract
This document does not have an outline. ... JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. ... Author links open the overlay panel. Numbers correspond to the affiliation list which can be exposed by using the show more link. ... 2-Trimethylsilyl-3-triflyl benzamide 3, undergoes fluoride-mediated 1,2-elimination to give the benzyne intermediate 4 which is trapped by cycloaddition (5), and nucleophilic reactions ...
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