The Journal of Organic Chemistry

Preparation and Some Reactions of Thiobis-N-(trifluoromethyl) amines1

TE STEVENS

Index: Stevens,T.E. Journal of Organic Chemistry, 1961 , vol. 26, p. 3451 - 3457

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Citation Number: 3

Abstract

The fluorination of aryl and alkyl isothiocyanates with iodine pentafluoride in pyridine solution has been found to produce thiobis-N-substituted iV-(trifluoromethy1) amines. The preparation and some of the reactions of these novel compounds are discussed. A unique rearrangement of a thioi) isaniinc to a diphenyl sulfide is reported.

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